Fast CO2 hydration kinetics impair heterogeneous but improve enzymatic CO2 reduction catalysis
The performance of heterogeneous catalysts for electrocatalytic CO 2 reduction suffers from
unwanted side reactions and kinetic inefficiencies at the required large overpotential. …
unwanted side reactions and kinetic inefficiencies at the required large overpotential. …
Interfacing formate dehydrogenase with metal oxides for the reversible electrocatalysis and solar‐driven reduction of carbon dioxide
M Miller, WE Robinson, AR Oliveira… - Angewandte Chemie …, 2019 - Wiley Online Library
The integration of enzymes with synthetic materials allows efficient electrocatalysis and
production of solar fuels. Here, we couple formate dehydrogenase (FDH) from Desulfovibrio …
production of solar fuels. Here, we couple formate dehydrogenase (FDH) from Desulfovibrio …
[HTML][HTML] Protein-and peptide-based biosensors in artificial olfaction
AJM Barbosa, AR Oliveira, ACA Roque - Trends in biotechnology, 2018 - cell.com
Animals' olfactory systems rely on proteins, olfactory receptors (ORs) and odorant-binding
proteins (OBPs), as their native sensing units to detect odours. Recent advances demonstrate …
proteins (OBPs), as their native sensing units to detect odours. Recent advances demonstrate …
A Semi‐artificial Photoelectrochemical Tandem Leaf with a CO2‐to‐Formate Efficiency Approaching 1 %
Semi‐artificial photoelectrochemistry can combine state‐of‐the‐art photovoltaic light‐absorbers
with enzymes evolved for selective fuel‐forming reactions such as CO 2 reduction, but …
with enzymes evolved for selective fuel‐forming reactions such as CO 2 reduction, but …
Toward the Mechanistic Understanding of Enzymatic CO2 Reduction
AR Oliveira, C Mota, C Mourato, RM Domingos… - ACS …, 2020 - ACS Publications
Reducing CO 2 is a challenging chemical transformation that biology solves easily, with high
efficiency and specificity. In particular, formate dehydrogenases are of great interest since …
efficiency and specificity. In particular, formate dehydrogenases are of great interest since …
The impact of the work-family conflict on employee engagement, performance, and turnover intention
Purpose The incompatibility between the sphere of work and the family is a reality that
plagues many workers today. The difficult articulation of these two domains leads to the …
plagues many workers today. The difficult articulation of these two domains leads to the …
An allosteric redox switch involved in oxygen protection in a CO2 reductase
Metal-dependent formate dehydrogenases reduce CO 2 with high efficiency and selectivity,
but are usually very oxygen sensitive. An exception is Desulfovibrio vulgaris W/Sec-FdhAB, …
but are usually very oxygen sensitive. An exception is Desulfovibrio vulgaris W/Sec-FdhAB, …
Understanding the local chemical environment of bioelectrocatalysis
…, SJ Cobb, AM Coito, AR Oliveira… - Proceedings of the …, 2022 - National Acad Sciences
Bioelectrochemistry employs an array of high-surface-area meso- and macroporous electrode
architectures to increase protein loading and the electrochemical current response. While …
architectures to increase protein loading and the electrochemical current response. While …
Formate Dehydrogenases Reduce CO2 Rather than HCO3−: An Electrochemical Demonstration
M Meneghello, AR Oliveira… - Angewandte Chemie …, 2021 - Wiley Online Library
Mo/W formate dehydrogenases catalyze the reversible reduction of CO 2 species to formate.
It is thought that the substrate is CO 2 and not a hydrated species like HCO 3 − , but there is …
It is thought that the substrate is CO 2 and not a hydrated species like HCO 3 − , but there is …
Self-report depressive symptoms do not directly predict suicidality in nonclinical individuals: Contributions toward a more psychosocial approach to suicide risk
…, RR Holden, P Laranjeira, T Troister, AR Oliveira… - Death studies, 2016 - Taylor & Francis
Although suicidality is associated with mental illness in general and depression in particular,
many depressed individuals do not attempt suicide and some individuals who attempt to or …
many depressed individuals do not attempt suicide and some individuals who attempt to or …